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Synergistic catalysis: enantioselective ring expansion of vinyl cyclopropanes combining 4 catalytic cycles. Synthesis of spiro-cyclopentanes bearing up to 4 stereocenters

Synergistic catalysis: enantioselective ring expansion of vinyl cyclopropanes combining 4 catalytic cycles. Synthesis of spiro-cyclopentanes bearing up to 4 stereocenters
Synergistic catalysis: enantioselective ring expansion of vinyl cyclopropanes combining 4 catalytic cycles. Synthesis of spiro-cyclopentanes bearing up to 4 stereocenters
A double synergistic cascade reaction is reported merging transition metal and amine catalysis. The reaction between vinyl cyclopropanes and enals render the final cyclopentane derivatives in excellent yields and stereoselectivities.

0947-6539
9923-9928
Meazza, Marta
c4665645-8c77-4cfd-aa02-6bcc3341c1aa
Rios Torres, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Meazza, Marta
c4665645-8c77-4cfd-aa02-6bcc3341c1aa
Rios Torres, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441

Meazza, Marta and Rios Torres, Ramon (2016) Synergistic catalysis: enantioselective ring expansion of vinyl cyclopropanes combining 4 catalytic cycles. Synthesis of spiro-cyclopentanes bearing up to 4 stereocenters. Chemistry - A European Journal, 22 (29), 9923-9928. (doi:10.1002/chem.201601893).

Record type: Article

Abstract

A double synergistic cascade reaction is reported merging transition metal and amine catalysis. The reaction between vinyl cyclopropanes and enals render the final cyclopentane derivatives in excellent yields and stereoselectivities.

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More information

Accepted/In Press date: 19 May 2016
e-pub ahead of print date: 8 June 2016
Published date: 11 July 2016
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 396471
URI: http://eprints.soton.ac.uk/id/eprint/396471
DOI: doi:10.1002/chem.201601893
ISSN: 0947-6539
PURE UUID: fa0a070d-b9f6-4780-ba71-c51e9b8b09f4
ORCID for Marta Meazza: ORCID iD orcid.org/0000-0003-4382-0626
ORCID for Ramon Rios Torres: ORCID iD orcid.org/0000-0002-3843-8521

Catalogue record

Date deposited: 09 Jun 2016 13:47
Last modified: 15 Mar 2024 05:38

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Contributors

Author: Marta Meazza ORCID iD
Author: Ramon Rios Torres ORCID iD

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