Electrosynthesis in extended channel length microfluidic cells
Electrosynthesis in extended channel length microfluidic cells
In recent papers, laboratory microfluidic electrolysis cells with extended channel lengths (0.7–2 m) and narrow
interelectrode gap (<0.5 mm) have been introduced; these cells permit high conversions at a flow rate consistent with the synthesis of products at a rate of multigrams/hour. Such microflow electrolysis cells must be operated with appropriate control parameters if good performance is to be achieved; thus, this paper emphasizes the correct selection of cell current, flow rate, and counter electrode chemistry. It is also shown that, within the limitations, the cells can be used for a number of electrosyntheses in the synthetic laboratory
191-197
Green, Robert
b94d81d2-c00e-4fcb-bbcd-2998250be0e9
Brown, Richard
21ce697a-7c3a-480e-919f-429a3d8550f5
Pletcher, Derek
f22ebe69-b859-4a89-80b0-9e190e6f8f30
11 October 2016
Green, Robert
b94d81d2-c00e-4fcb-bbcd-2998250be0e9
Brown, Richard
21ce697a-7c3a-480e-919f-429a3d8550f5
Pletcher, Derek
f22ebe69-b859-4a89-80b0-9e190e6f8f30
Green, Robert, Brown, Richard and Pletcher, Derek
(2016)
Electrosynthesis in extended channel length microfluidic cells.
Journal of Flow Chemistry, 6 (3), .
(doi:10.1556/1846.2016.00028).
Abstract
In recent papers, laboratory microfluidic electrolysis cells with extended channel lengths (0.7–2 m) and narrow
interelectrode gap (<0.5 mm) have been introduced; these cells permit high conversions at a flow rate consistent with the synthesis of products at a rate of multigrams/hour. Such microflow electrolysis cells must be operated with appropriate control parameters if good performance is to be achieved; thus, this paper emphasizes the correct selection of cell current, flow rate, and counter electrode chemistry. It is also shown that, within the limitations, the cells can be used for a number of electrosyntheses in the synthetic laboratory
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More information
Accepted/In Press date: 30 August 2016
Published date: 11 October 2016
Additional Information:
Funded by EPSRC: Factory in a Fumehood: Reagentless Flow Reactors as Enabling Techniques for Manufacture (EP/L003325/1)
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 400530
URI: http://eprints.soton.ac.uk/id/eprint/400530
ISSN: 2062-249X
PURE UUID: 929fb7c8-725d-441e-bbe1-0af1b1614cec
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Date deposited: 16 Sep 2016 11:05
Last modified: 15 Mar 2024 02:53
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Author:
Robert Green
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