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Formation and structural characterization of metal complexes derived from thiosalicylic acid

Formation and structural characterization of metal complexes derived from thiosalicylic acid
Formation and structural characterization of metal complexes derived from thiosalicylic acid
The formation and structural aspects of some metal complexes of thiosalicylic acid (TSA) were studied. The μ-bridging tetra-coordinated Ru complex, [Ru(C6H4(CO2)(μ-S)(H2O)]2 (1) was formed by hydrothermal reaction of TSA with RuCl3. The complexes [M(dtdb)(phen)(H2O)]n (2–4) (M = ZnII, CoII, NiII, dtdb = 2,2′-dithiodibenzoate anion, phen = 1,10-phenanthroline) were obtained by the slow diffusion technique and the in situ S–S bond formation was confirmed by elemental, spectral and X-ray analysis. Reaction of TSA with CuCl2 and 2,2′-bipyridine (bipy) under the slow diffusion technique yielded the dimer [Cu(tdb)(bipy)] (5) (tdb = thiodibenzoic acid), where the in situ generation of 2,2′-thiodibenzoic acid was observed.
0044-2313
1167-1172
Bhowon, Minu G.
45e39fba-0c1e-4681-a9d2-c0eb0a6fd9f8
Jhaumeer-laulloo, Sabina
bd5d508c-5e93-4c98-992d-cb06ba300477
Moosun, Salma
0e5daeac-73d7-4dc7-b68d-613ac2d27759
Humphreys, Lisa
f78709c9-36a1-4a01-9c37-c8276c509260
Coles, Simon
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Fowdram, Roshni
fe89aa44-edb1-4979-8766-419d8726c9f1
Mungra, Evena
d5c93c1a-7742-493b-9340-c892c8f32332
Bhowon, Minu G.
45e39fba-0c1e-4681-a9d2-c0eb0a6fd9f8
Jhaumeer-laulloo, Sabina
bd5d508c-5e93-4c98-992d-cb06ba300477
Moosun, Salma
0e5daeac-73d7-4dc7-b68d-613ac2d27759
Humphreys, Lisa
f78709c9-36a1-4a01-9c37-c8276c509260
Coles, Simon
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Fowdram, Roshni
fe89aa44-edb1-4979-8766-419d8726c9f1
Mungra, Evena
d5c93c1a-7742-493b-9340-c892c8f32332

Bhowon, Minu G., Jhaumeer-laulloo, Sabina, Moosun, Salma, Humphreys, Lisa, Coles, Simon, Fowdram, Roshni and Mungra, Evena (2017) Formation and structural characterization of metal complexes derived from thiosalicylic acid. Zeitschrift für anorganische und allgemeine Chemie, 643 (18), 1167-1172. (doi:10.1002/zaac.201700244).

Record type: Article

Abstract

The formation and structural aspects of some metal complexes of thiosalicylic acid (TSA) were studied. The μ-bridging tetra-coordinated Ru complex, [Ru(C6H4(CO2)(μ-S)(H2O)]2 (1) was formed by hydrothermal reaction of TSA with RuCl3. The complexes [M(dtdb)(phen)(H2O)]n (2–4) (M = ZnII, CoII, NiII, dtdb = 2,2′-dithiodibenzoate anion, phen = 1,10-phenanthroline) were obtained by the slow diffusion technique and the in situ S–S bond formation was confirmed by elemental, spectral and X-ray analysis. Reaction of TSA with CuCl2 and 2,2′-bipyridine (bipy) under the slow diffusion technique yielded the dimer [Cu(tdb)(bipy)] (5) (tdb = thiodibenzoic acid), where the in situ generation of 2,2′-thiodibenzoic acid was observed.

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Thiolato paper revised version LH review - Accepted Manuscript
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Accepted/In Press date: 25 July 2017
e-pub ahead of print date: 1 September 2017
Published date: 4 October 2017

Identifiers

Local EPrints ID: 415375
URI: https://eprints.soton.ac.uk/id/eprint/415375
ISSN: 0044-2313
PURE UUID: 4ee79307-a06d-4679-975e-6364307db800
ORCID for Simon Coles: ORCID iD orcid.org/0000-0001-8414-9272

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Date deposited: 08 Nov 2017 17:30
Last modified: 20 Jul 2019 04:44

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