Ponce De Leon Albarran, Carlos, Schoetz, Theresa, Bund, A. and Ueda, M. (2018) Electro-polymerisation and characterisation of PEDOT in Lewis basic, neutral and acidic EMImCl-AlCl3 ionic liquid. Electrochimica Acta. (doi:10.1016/j.electacta.2018.01.033).
Abstract
This work studied the electro-polymerisation of 3,4-ethylenedioxythiophene (EDOT) and its electrochemical behavior in Lewis acidic, neutral and basic chloroaluminate ionic liquid 1-ethyl-3-methylimidazolium chloride aluminum chloride (EMImCl-AlCl3) by cyclic voltammetry. It was found that the electro-polymerisation on vitreous carbon only occurs in Lewis neutral EMImCl-AlCl3 as a dark blue-violet film whereas the electro-polymerisation in a Lewis acidic or basic compositions is not possible due to the interactions between the conductive polymer and the ionic liquid as well as the potential stability limits of the electrolyte. PEDOT films synthesised in Lewis neutral ionic liquid were tested in monomer-free Lewis acidic, basic and neutral EMImCl-AlCl3 and show different doping and de-doping behavior for chloride ionic species. The PEDOT films in a Lewis neutral composition showed higher doping levels due to the higher potential stability window, up to 2.6 V vs. Al|Al(III) than in a Lewis acidic and basic solutions. Furthermore, it was shown that the doping and de-doping levels are predefined during the electro-polymerisation of PEDOT. The anion doping and de-doping reaction reached 97% reversibility in the neutral composition, which suggests that PEDOT is a suitable electrode material to store charged species in this media and could be used in rechargeable energy storage devices.
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- Faculties (pre 2018 reorg) > Faculty of Engineering and the Environment (pre 2018 reorg) > Southampton Marine & Maritime Institute (pre 2018 reorg)
- Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg) > Institute for Life Sciences (pre 2018 reorg)
Current Faculties > Faculty of Environmental and Life Sciences > Institute for Life Sciences > Institute for Life Sciences (pre 2018 reorg)
Institute for Life Sciences > Institute for Life Sciences (pre 2018 reorg) - Faculties (pre 2018 reorg) > Faculty of Engineering and the Environment (pre 2018 reorg) > Mechanical Engineering (pre 2018 reorg) > Energy Technology Group (pre 2018 reorg)
Current Faculties > Faculty of Engineering and Physical Sciences > School of Engineering > Mechanical Engineering > Mechanical Engineering (pre 2018 reorg) > Energy Technology Group (pre 2018 reorg)
Mechanical Engineering > Mechanical Engineering (pre 2018 reorg) > Energy Technology Group (pre 2018 reorg) - Faculties (pre 2018 reorg) > Faculty of Engineering and the Environment (pre 2018 reorg) > Education Hub (pre 2018 reorg)
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