3.9 µm emission in Nd3+ sensitized Ho3+ doped fluoroaluminate glasses
3.9 µm emission in Nd3+ sensitized Ho3+ doped fluoroaluminate glasses
Ho3+ and Nd3+/Ho3+ doped fluoroaluminate glass samples were fabricated by the melt-quenching method and showed high transmittance and a wide transparency window. Under 808 nm pumping, emission at 3.9 µm, corresponding to the Ho: 5I5→5I6 transition, was observed. The presence of Nd3+ strongly enhances the Ho3+ emission. The emission and absorption cross-sections were calculated using the Judd-Ofelt, Füchtbauer-Ladenburg and McCumber theories and the energy transfer mechanism between Nd3+ and Ho3+ was analyzed. The most efficient 3.9 µm emission was obtained when the concentration ratio of Nd3+: Ho3+ is 1:2.
3.9 µm, Fluoroaluminate glass, Mid-infrared fluorescence, Nd /Ho -codoped
Zhang, Jiquan
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Zhao, Haiyan
032a2c46-295a-4aa5-8bea-a66d71af2153
Wang, Ruicong
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Li, Angzhen
2a6ff87d-2b65-488b-a27e-3e6c04887105
Zhang, Jie
21de2303-4727-4097-9b0f-ae43d95d052a
Jia, Shijie
1f2ca0bb-c36c-4d5a-af56-3f8b3cd80be0
Brambilla, Gilberto
815d9712-62c7-47d1-8860-9451a363a6c8
Wang, Shunbin
70976916-f2c8-4a61-b0ba-2cdd77286bea
Wang, Pengfei
a1ba240f-d4f0-4150-bcd8-cb418e841dcb
31 December 2021
Zhang, Jiquan
cf0cf01c-73af-4c49-aa26-da6c46969a5b
Zhao, Haiyan
032a2c46-295a-4aa5-8bea-a66d71af2153
Wang, Ruicong
0bc4cb0f-e2a2-450f-8d0d-1e5601d69ccb
Li, Angzhen
2a6ff87d-2b65-488b-a27e-3e6c04887105
Zhang, Jie
21de2303-4727-4097-9b0f-ae43d95d052a
Jia, Shijie
1f2ca0bb-c36c-4d5a-af56-3f8b3cd80be0
Brambilla, Gilberto
815d9712-62c7-47d1-8860-9451a363a6c8
Wang, Shunbin
70976916-f2c8-4a61-b0ba-2cdd77286bea
Wang, Pengfei
a1ba240f-d4f0-4150-bcd8-cb418e841dcb
Zhang, Jiquan, Zhao, Haiyan, Wang, Ruicong, Li, Angzhen, Zhang, Jie, Jia, Shijie, Brambilla, Gilberto, Wang, Shunbin and Wang, Pengfei
(2021)
3.9 µm emission in Nd3+ sensitized Ho3+ doped fluoroaluminate glasses.
Journal of Alloys and Compounds, 889, [161684].
(doi:10.1016/j.jallcom.2021.161684).
Abstract
Ho3+ and Nd3+/Ho3+ doped fluoroaluminate glass samples were fabricated by the melt-quenching method and showed high transmittance and a wide transparency window. Under 808 nm pumping, emission at 3.9 µm, corresponding to the Ho: 5I5→5I6 transition, was observed. The presence of Nd3+ strongly enhances the Ho3+ emission. The emission and absorption cross-sections were calculated using the Judd-Ofelt, Füchtbauer-Ladenburg and McCumber theories and the energy transfer mechanism between Nd3+ and Ho3+ was analyzed. The most efficient 3.9 µm emission was obtained when the concentration ratio of Nd3+: Ho3+ is 1:2.
Text
Revised-JALCOM-D-21-06895_V1_ZJQ
- Accepted Manuscript
More information
Accepted/In Press date: 21 August 2021
e-pub ahead of print date: 25 August 2021
Published date: 31 December 2021
Keywords:
3.9 µm, Fluoroaluminate glass, Mid-infrared fluorescence, Nd /Ho -codoped
Identifiers
Local EPrints ID: 453102
URI: http://eprints.soton.ac.uk/id/eprint/453102
ISSN: 0925-8388
PURE UUID: 2e82e603-2443-4c46-bfc3-037ded158be9
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Date deposited: 08 Jan 2022 20:32
Last modified: 17 Mar 2024 07:01
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Contributors
Author:
Jiquan Zhang
Author:
Haiyan Zhao
Author:
Ruicong Wang
Author:
Angzhen Li
Author:
Jie Zhang
Author:
Shijie Jia
Author:
Gilberto Brambilla
Author:
Shunbin Wang
Author:
Pengfei Wang
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