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Theory and applications of supercycled symmetry-based recoupling sequences in solid-state NMR

Theory and applications of supercycled symmetry-based recoupling sequences in solid-state NMR
Theory and applications of supercycled symmetry-based recoupling sequences in solid-state NMR
We present the theoretical principles of supercycled symmetry-based recoupling sequences in solid-state magic-angle-spinning NMR. We discuss the construction procedure of the SR26 pulse sequence, which is a particularly robust sequence for double-quantum homonuclear dipole-dipole recoupling. The supercycle removes destructive higher-order average Hamiltonian terms and renders the sequence robust over long time intervals. We demonstrate applications of the SR26 sequence to double-quantum spectroscopy, homonuclear spin counting, and determination of the relative orientations of chemical shift anisotropy tensors.
0021-9606
1-19
Kristiansen, Per Eugen
3f7f4299-868f-4127-bf96-9cc6253f0c5e
Carravetta, Marina
1b12fa96-4a6a-4689-ab3b-ccc68f1d7691
van Beek, Jacco D.
ba9e0c40-f430-4e55-bdbc-c506abae7112
Lai, Wai Cheu
29df4026-12c5-4a02-a271-8e7d19c10ec0
Levitt, Malcolm H.
bcc5a80a-e5c5-4e0e-9a9a-249d036747c3
Kristiansen, Per Eugen
3f7f4299-868f-4127-bf96-9cc6253f0c5e
Carravetta, Marina
1b12fa96-4a6a-4689-ab3b-ccc68f1d7691
van Beek, Jacco D.
ba9e0c40-f430-4e55-bdbc-c506abae7112
Lai, Wai Cheu
29df4026-12c5-4a02-a271-8e7d19c10ec0
Levitt, Malcolm H.
bcc5a80a-e5c5-4e0e-9a9a-249d036747c3

Kristiansen, Per Eugen, Carravetta, Marina, van Beek, Jacco D., Lai, Wai Cheu and Levitt, Malcolm H. (2006) Theory and applications of supercycled symmetry-based recoupling sequences in solid-state NMR. The Journal of Chemical Physics, 124 (234510), 1-19. (doi:10.1063/1.2205857).

Record type: Article

Abstract

We present the theoretical principles of supercycled symmetry-based recoupling sequences in solid-state magic-angle-spinning NMR. We discuss the construction procedure of the SR26 pulse sequence, which is a particularly robust sequence for double-quantum homonuclear dipole-dipole recoupling. The supercycle removes destructive higher-order average Hamiltonian terms and renders the sequence robust over long time intervals. We demonstrate applications of the SR26 sequence to double-quantum spectroscopy, homonuclear spin counting, and determination of the relative orientations of chemical shift anisotropy tensors.

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Published date: 21 June 2006
Organisations: Chemistry

Identifiers

Local EPrints ID: 46683
URI: http://eprints.soton.ac.uk/id/eprint/46683
ISSN: 0021-9606
PURE UUID: 1e1600c1-fcb3-4035-a26f-60db5f012fe9
ORCID for Marina Carravetta: ORCID iD orcid.org/0000-0002-6296-2104
ORCID for Malcolm H. Levitt: ORCID iD orcid.org/0000-0001-9878-1180

Catalogue record

Date deposited: 12 Jul 2007
Last modified: 26 Nov 2019 01:52

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