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Wear Mechanisms of Cold-Sprayed Stellite-6 During Reciprocated Dry Sliding Under Different Sliding Speeds

Wear Mechanisms of Cold-Sprayed Stellite-6 During Reciprocated Dry Sliding Under Different Sliding Speeds
Wear Mechanisms of Cold-Sprayed Stellite-6 During Reciprocated Dry Sliding Under Different Sliding Speeds

Cobalt–chromium alloys are often employed in those environments that require reliable wear and friction properties. Cold Gas Dynamic Spray offers the opportunity to obtain good quality deposits of Stellite-6, that can be successfully used in harsh environments, where good surface performance, in terms of wear resistance, is required. It is also well-known that Stellite-6 is subjected to several physical changes at the interface during dry sliding, that are often related to the loading conditions. As a consequence, wear behavior of this alloy can undergo some variations that linear models are not able to capture, since micro-structural modifications occur during operation. To better understand the wear mechanisms of cold-sprayed Stellite-6 coatings together with the occurring physical phenomena, a systematic experimental study was performed, in fact, to date, no such in-depth tribological studies have been performed. Tests were conducted under combinations of two sliding speeds (0.1 and 0.5 m/s) and four contact pressure in the range of 2-5 MPa. In low-speed tests, abrasive wear is evident, where detachment and pull-out phenomena mainly affect the worn surface of coatings. On the other hand, subsurface cracking was observed in high-speed tests, as well as evidence of plastic deformation on the wear surface. These results suggest that observed wear mechanisms are more likely a consequence of adhesive wear. Unique to this study, the cross-sectional nano-indentation tests showed how the stiffness of the coating, near to wear interface, increases significantly in the case of the lowest value of sliding speed (i.e., v = 0.1 m/s), whereas tends to decrease at high speeds, i.e., v = 0.5 m/s, as a consequence of the formation of subsurface cracks into the coating.

cold gas dynamic spray, dry sliding, indentation, platelet, pull-out, stellite
1059-9630
2336–2350
Wood, Robert
d9523d31-41a8-459a-8831-70e29ffe8a73
Magaro, Pietro
dfc888c8-a393-41b3-a8d9-d5d47b629594
Furgiuele, F.
4edf942b-70f4-43a6-b321-462e3027bc4a
Maletta, C.
b2a354f6-2632-4a7b-bf37-e4c8b4a9231a
Tului, M
487de5c8-73ff-4cb8-a022-3087bbe2bfe1
Wood, Robert
d9523d31-41a8-459a-8831-70e29ffe8a73
Magaro, Pietro
dfc888c8-a393-41b3-a8d9-d5d47b629594
Furgiuele, F.
4edf942b-70f4-43a6-b321-462e3027bc4a
Maletta, C.
b2a354f6-2632-4a7b-bf37-e4c8b4a9231a
Tului, M
487de5c8-73ff-4cb8-a022-3087bbe2bfe1

Wood, Robert, Magaro, Pietro, Furgiuele, F., Maletta, C. and Tului, M (2023) Wear Mechanisms of Cold-Sprayed Stellite-6 During Reciprocated Dry Sliding Under Different Sliding Speeds. Journal of Thermal Spray Technology, 32 (8), 2336–2350. (doi:10.1007/s11666-023-01643-w).

Record type: Article

Abstract

Cobalt–chromium alloys are often employed in those environments that require reliable wear and friction properties. Cold Gas Dynamic Spray offers the opportunity to obtain good quality deposits of Stellite-6, that can be successfully used in harsh environments, where good surface performance, in terms of wear resistance, is required. It is also well-known that Stellite-6 is subjected to several physical changes at the interface during dry sliding, that are often related to the loading conditions. As a consequence, wear behavior of this alloy can undergo some variations that linear models are not able to capture, since micro-structural modifications occur during operation. To better understand the wear mechanisms of cold-sprayed Stellite-6 coatings together with the occurring physical phenomena, a systematic experimental study was performed, in fact, to date, no such in-depth tribological studies have been performed. Tests were conducted under combinations of two sliding speeds (0.1 and 0.5 m/s) and four contact pressure in the range of 2-5 MPa. In low-speed tests, abrasive wear is evident, where detachment and pull-out phenomena mainly affect the worn surface of coatings. On the other hand, subsurface cracking was observed in high-speed tests, as well as evidence of plastic deformation on the wear surface. These results suggest that observed wear mechanisms are more likely a consequence of adhesive wear. Unique to this study, the cross-sectional nano-indentation tests showed how the stiffness of the coating, near to wear interface, increases significantly in the case of the lowest value of sliding speed (i.e., v = 0.1 m/s), whereas tends to decrease at high speeds, i.e., v = 0.5 m/s, as a consequence of the formation of subsurface cracks into the coating.

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Accepted/In Press date: 31 July 2023
e-pub ahead of print date: 16 August 2023
Published date: December 2023
Additional Information: Funding Information: Nanoindentation experiments were carried out in the "MaTeRiA Laboratory" (University of Calabria), funded by "Pon Ricerca e Competitività 2007/2013." Wear experiments were carried out at the national Centre for Advanced Tribology at Southampton (nCATS). The authors would like to give special thanks to Dr. Zaihao Tian for performing the SEM analysis. Funding Information: Nanoindentation experiments were carried out in the "MaTeRiA Laboratory" (University of Calabria), funded by "Pon Ricerca e Competitività 2007/2013." Wear experiments were carried out at the national Centre for Advanced Tribology at Southampton (nCATS). The authors would like to give special thanks to Dr. Zaihao Tian for performing the SEM analysis. Publisher Copyright: © 2023, The Author(s).
Keywords: cold gas dynamic spray, dry sliding, indentation, platelet, pull-out, stellite

Identifiers

Local EPrints ID: 481016
URI: http://eprints.soton.ac.uk/id/eprint/481016
ISSN: 1059-9630
PURE UUID: 751b7401-ad9d-482d-b885-a451bcede439
ORCID for Robert Wood: ORCID iD orcid.org/0000-0003-0681-9239

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Date deposited: 14 Aug 2023 17:11
Last modified: 18 Mar 2024 02:40

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Contributors

Author: Robert Wood ORCID iD
Author: Pietro Magaro
Author: F. Furgiuele
Author: C. Maletta
Author: M Tului

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