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Impact of disinfectant on the electrical outputs of urine-fed ceramic and membrane-less microbial fuel cell cascades

Impact of disinfectant on the electrical outputs of urine-fed ceramic and membrane-less microbial fuel cell cascades
Impact of disinfectant on the electrical outputs of urine-fed ceramic and membrane-less microbial fuel cell cascades
The application of microbial fuel cells in sanitation has demonstrated feasibility in supplying electricity and providing safety in underserved communities, especially at toilet blocks. Two different designs of urine fed MFC cascades, ceramic MFCs (c-MFC) and self-stratifying MFCs (s-MFC), have been employed in large-scale feasibility studies. As part of a pre-commercialisation approach, this study verified the resilience of each design when a commercial disinfectant was introduced into the system. Five different conditions, varying in concentrations (24.2 mM–604.5 mM) and the total volume (50–500 mL) of sodium hypochlorite disinfectant introduced, were tested. Upon adding the disinfectant, both types of MFC-cascades exhibited rapid power drops with response times lower than 5 min in all tested conditions, followed by relatively swift recovery times of up to 250 min. The volume of disinfectant introduced had a greater impact on power output than its concentration or dose. Comparing the two designs, the c-MFC demonstrated a much larger voltage drop, up to 0 mV, and shorter recovery time compared to the s-MFC under most test conditions, mainly attributed to the presence (c-MFC) or absence (s-MFC) of a membrane. Overall, both types of MFCs exhibited strong resilience to sodium hypochlorite additions, thereby highlighting the commercial potential of the technology towards safe off-grid sanitation.
0360-3199
759-763
You, Jiseon
1442df08-0ea4-4134-b6be-6b773b05f58d
Walter, Xavier Alexis
67c83b61-76af-4e37-aec8-79ebc723b807
Gajda, Iwona
943dd6bd-524b-4c7b-b794-dec5ee8014b7
Greenman, John
eb3d9b82-7cac-4442-9301-f34884ae4a16
Ieropoulos, Ioannis
6c580270-3e08-430a-9f49-7fbe869daf13
You, Jiseon
1442df08-0ea4-4134-b6be-6b773b05f58d
Walter, Xavier Alexis
67c83b61-76af-4e37-aec8-79ebc723b807
Gajda, Iwona
943dd6bd-524b-4c7b-b794-dec5ee8014b7
Greenman, John
eb3d9b82-7cac-4442-9301-f34884ae4a16
Ieropoulos, Ioannis
6c580270-3e08-430a-9f49-7fbe869daf13

You, Jiseon, Walter, Xavier Alexis, Gajda, Iwona, Greenman, John and Ieropoulos, Ioannis (2024) Impact of disinfectant on the electrical outputs of urine-fed ceramic and membrane-less microbial fuel cell cascades. International Journal of Hydrogen Energy, 57, 759-763. (doi:10.1016/j.ijhydene.2024.01.042).

Record type: Article

Abstract

The application of microbial fuel cells in sanitation has demonstrated feasibility in supplying electricity and providing safety in underserved communities, especially at toilet blocks. Two different designs of urine fed MFC cascades, ceramic MFCs (c-MFC) and self-stratifying MFCs (s-MFC), have been employed in large-scale feasibility studies. As part of a pre-commercialisation approach, this study verified the resilience of each design when a commercial disinfectant was introduced into the system. Five different conditions, varying in concentrations (24.2 mM–604.5 mM) and the total volume (50–500 mL) of sodium hypochlorite disinfectant introduced, were tested. Upon adding the disinfectant, both types of MFC-cascades exhibited rapid power drops with response times lower than 5 min in all tested conditions, followed by relatively swift recovery times of up to 250 min. The volume of disinfectant introduced had a greater impact on power output than its concentration or dose. Comparing the two designs, the c-MFC demonstrated a much larger voltage drop, up to 0 mV, and shorter recovery time compared to the s-MFC under most test conditions, mainly attributed to the presence (c-MFC) or absence (s-MFC) of a membrane. Overall, both types of MFCs exhibited strong resilience to sodium hypochlorite additions, thereby highlighting the commercial potential of the technology towards safe off-grid sanitation.

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Accepted/In Press date: 3 January 2024
e-pub ahead of print date: 15 January 2024
Published date: 29 February 2024

Identifiers

Local EPrints ID: 500811
URI: http://eprints.soton.ac.uk/id/eprint/500811
ISSN: 0360-3199
PURE UUID: 6c46e0e5-5dca-4169-979a-bd675fc1dc88
ORCID for Ioannis Ieropoulos: ORCID iD orcid.org/0000-0002-9641-5504

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Date deposited: 13 May 2025 17:14
Last modified: 22 Aug 2025 02:34

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Contributors

Author: Jiseon You
Author: Xavier Alexis Walter
Author: Iwona Gajda
Author: John Greenman

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