Data for the paper entitled: Decolorization of Reactive Black-5 at an RVC substrate decorated with PbO2/ TiO2 nanosheets prepared by anodic electrodeposition

Abstract

Data supports S.Z.J. Zaidi, C. Harito, F.C. Walsh, C. Ponce de León (2018). Decolorization of Reactive Black-5 at an RVC substrate decorated with PbO2/ TiO2 nanosheets prepared by anodic electrodeposition. Journal of Solid State Electrochemistry Reticulated vitreous carbon (RVC) substrates were coated with a composite of PbO2 and titanate nanosheets (TiNS) by anodic electrophoretic deposition. The structure and morphological characteristics of the coating were evaluated by Field Emission Scanning Electron Microscopy (FESEM) and Raman spectroscopy. The TiNS/PbO2/RVC coating contained the anatase phase and showed a well-defined, microporous morphology with hydrophilic character along the length and thickness of the RVC struts. Electrochemical and photocatalytic activity of the coatings facilitated RB-5 dye degradation as a model organic pollutant in wastewater. The electrochemical decolorization involves the generation of hydroxyl free radicals over the TiNS/PbO2/RVC anode composite surface whereas photocatalytic decolorization was driven by the synergetic photocatalytic effect imparted by the photoinduced holes and free electron acceptors. The photocatalytic properties of the TiNS/PbO2 coating were achieved by calcination at 450 °C for 60 minutes in air which converted the titanate phase to anatase and modified its surface area. This enabled 98 % electrochemical decolorization of the RB-5 dye solution (measured by visible absorption at 597 nm) in a time of 60 minutes.

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